2022高一英语周报外研答案

20.(10分)(1)334分)Na乎2Na+(1分)(2)与过量的S2结合生成FeS沉淀,防止As2S3与S2结合生成AsS3-(或与S2-结合生成FeS沉淀,使平衡左移,提高沉砷效果)(2分)3)稀硫酸、铁氰化钾溶液(或稀硫酸、高锰酸钾溶液)(2分)(4)2AsO-+2SO2+2H+=As2O3↓+2SO-+H2O(2分)(5)SO2(2分)【解析】(1)砷元素的原子序数为33,Na2S的电子式为Nat[S乎2Na+。(2)“沉砷”中FeSO4的作用是Fe2与过量的S2-结合生成FeS沉淀,防止As2S3与S2结合生成AsS3-或与S2-结合生成FeS沉淀,使平衡左移,提高沉砷效果(3)四氧化三铁中含有+2价铁,具有还原性,证明四氧化三铁存在的试剂为稀硫酸铁氰化钾溶液或稀硫酸、髙锰酸钾溶液(4)调节pH=0时,由Na3AsO4制备A2O3的离子方程式为2AO-+2SO2+2H+==As2O3↓+a2SO2-+H2O5)AsS4中As元素为+2价、S元素为-2价,1 mol As S4参加反应时,转移28mole,则S元素的化合价升高6价,物质a为SO2。

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